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Iron oxide-apatite (IOA) deposits, also known as magnetite-apatite or Kiruna-type deposits, are a major source of iron and potentially of rare earth elements and phosphorus. To date, the youngest representative of this group is the Pleistocene (~2 Ma) El Laco deposit, located in the Andean Cordillera of northern Chile. El Laco is considered a unique type of IOA deposit because of its young age and its volcanic-like features. Here we report the occurrence of similarly young IOA-type mineralization hosted within the Laguna del Maule Volcanic Complex, an unusually large and recent silicic volcanic system in the south-central Andes. We combined field observations and aerial drone images with detailed petrographic observations, electron microprobe analysis (EMPA), and 40Ar/39Ar dating to characterize the magnetite mineralization—named here “Vetas del Maule”—hosted within andesites of the now extinct La Zorra volcano (40Ar/39Ar plateau age of 1.013 ± 0.028 Ma). Five different styles of magnetite mineralization were identified: (1) massive magnetite, (2) pyroxene-actinolite-magnetite veins, (3) magnetite hydrothermal breccias, (4) disseminated magnetite, and (5) pyroxene-actinolite veins with minor magnetite. Field observations and aerial drone imaging, coupled with microtextural and microanalytical data, suggest a predominantly hydrothermal origin for the different types of mineralization. 40Ar/39Ar incremental heating of phlogopite associated with the magnetite mineralization yielded a plateau age of 873.6 ± 30.3 ka, confirming that the emplacement of Vetas del Maule postdated that of the host andesite rocks. Our data support the hypothesis that the magnetite mineralization formed in a volcanic setting from Fe-rich fluids exsolved from a magma at depth. Ultimately, Vetas del Maule provides evidence that volcanic-related IOA mineralization may be more common than previously thought, opening new opportunities of research and exploration for this ore deposit type in active volcanic arcs. 

Abstract Clinopyroxene is a rock-forming mineral that commonly hosts melt inclusions in mafic to intermediate composition volcanic and plutonic rocks. It is highly resistant to alteration compared to other co-existing phenocrysts such as plagioclase. Several recent studies have 40Ar/39Ar dated clinopyroxene in Neoproterozoic to Miocene basalts and dolerites. To assess the viability of the technique at the youngest end of the geologic time scale, we performed 40Ar/39Ar incremental heating experiments on clinopyroxene-hosted melt inclusions from a variety of mafic lithologies and tectonic settings. Most samples produced precise plateau ages including several Quaternary basalts to andesites as young as 0.6 Ma. All data are indistinguishable from new and/or published 40Ar/39Ar ages on groundmass or plagioclase from the same samples. The source of potassium (K) and resulting 40Ar* within clinopyroxene has been debated, but thus far has only been inferred based on 40Ar/39Ar data. Using electron probe microanalysis (EPMA) we show that there is negligible K in the clinopyroxene host, but substantial K (e.g., 1–4 wt%) in trapped melt inclusions and minor amounts in plagioclase inclusions. Thus, melt inclusions, which are common in phenocrysts in basaltic magmas, can be used to obtain accurate and precise 40Ar/39Ar ages for difficult-to-date volcanic and plutonic rocks from the Precambrian to the Pleistocene. 

Sedimentary basins record crustal-scale tectonic processes related to the construction and demise of orogenic belts, making them an invaluable archive for the reconstruction of the evolution of the North American Cordillera. In southwest Montana, USA, the Renova Formation, considered to locally represent the earliest accumulation following Mesozoic−Cenozoic compressional deformation, is widespread but remains poorly dated, and its origin is debated. Herein, we employed detrital zircon U-Pb and (U-Th)/He double dating and sanidine 40Ar/39Ar geochronology in the context of decimeter-scale measured stratigraphic sections in the Renova Formation of the Muddy Creek Basin to determine basin evolution and sediment provenance and place the basin-scale record within a regional context to illuminate the lithospheric processes driving extension and subsidence. The Muddy Creek Basin is an extensional half graben in southwest Montana that is ∼22 km long and ∼7 km wide, with a >800-m-thick sedimentary package. Basin deposition began ca. 49 Ma, as marked by multiple ignimbrites sourced from the Challis volcanic field, which are overlain by a tuffaceous fluvial section. Fluvial strata are capped by a 46.8 Ma Challis ignimbrite constrained by sanidine 40Ar/39Ar dating. An overlying fossiliferous limestone records the first instance of basinal ponding, which was coeval with the cessation of delivery of Challis volcanics−derived sediment into the Green River Basin. We attribute initial ponding to regional drainage reorganization and damning of the paleo−Idaho River due to uplift and doming of the southern Absaroka volcanic province, resulting in its diversion away from the Green River Basin and backfilling of the Lemhi Pass paleovalley. Detrital zircon maximum depositional ages and sanidine 40Ar/39Ar ages show alternating fluvial sandstone and lacustrine mudstone deposition from 46 Ma to 40 Ma in the Muddy Creek Basin. Sediment provenance was dominated by regionally sourced, Challis volcanics−aged and Idaho Batholith−aged grains, while detrital zircon (U-Th)/He (ZHe) data are dominated by Eocene cooling ages. Basin deposition became fully lacustrine by ca. 40 Ma, based on an increasing frequency of organic-rich mudstone with rare interbedded sandstone. Coarse-grained lithofacies became prominent again starting ca. 37 Ma, coeval with a major shift in sediment provenance due to extension and local footwall unroofing. Detrital zircon U-Pb and corresponding ZHe ages from the upper part of the section are predominantly Paleozoic in age, sourced from the Paleozoic sedimentary strata exposed in the eastern footwall of the Muddy Creek detachment fault. Paleocurrents shift from south- to west-directed trends, supporting the shift to local sources, consistent with initiation of the Muddy Creek detachment fault. Detrital zircon maximum depositional ages from the youngest strata in the basin suggest deposition continuing until at least 36 Ma. These data show that extension in the Muddy Creek Basin, which we attribute to continued lithospheric thermal weakening, initiated ∼10 m.y. later than in the Anaconda and Bitterroot metamorphic core complexes. This points to potentially different drivers of extension in western Montana and fits previously proposed models of a regional southward sweep of extension related to Farallon slab removal. 

Mocho-Choshuenco volcano (39.9°S, 72.0°W) produced ∼75 explosive eruptions following retreat of the >1.5-km-thick Patagonian Ice Sheet associated with the local Last Glacial Maximum (LGM, from 35 to 18 ka). Here, we extend this record of volcanic evolution to include pre- and syn-LGM lavas that erupted during the Pleistocene. We establish a long-term chronology of magmatic and volcanic evolution and evaluate the relationship between volcanism and loading/unloading of the Patagonian Ice Sheet via twenty-four 40Ar/39Ar and two 3He age determinations integrated with stratigraphy and whole-rock compositions of lava flows and glass compositions of tephra. Our findings reveal that the edifice is much younger than previously thought and preserves 106 km3 of eruptive products, of which 50% were emplaced immediately following the end of the penultimate glaciation and 20% after the end of the LGM. A period of volcanic inactivity between 37 and 26 ka, when glaciers expanded, was followed by the eruption of incompatible element-rich basaltic andesites. Several of these syn-LGM lavas dated between 26 and 16 ka, which crop out at 1500−1700 m above sea level, show ice contact features that are consistent with emplacement against a 1400- to 1600-m-thick Patagonian Ice Sheet. Small volume dacitic eruptions and two explosive rhyolitic eruptions dominate the volcanic output from 18 to 8 ka, when the Patagonian Ice Sheet began to retreat rapidly. We hypothesize that increased lithostatic loading as the Patagonian Ice Sheet grew prohibited dike propagation, thus stalling the ascent of magma, promoting growth of at least three discrete magma reservoirs, and enhancing minor crustal assimilation to generate incompatible element-rich basaltic andesitic to dacitic magmas that erupted between 26 and 17 ka. From an adjacent reservoir, incompatible element-poor dacites erupted from 17 to 12 ka. These lava flows were followed by the caldera-forming eruption at 11.5 ka of 5.3 km3 of rhyolite from a deeper reservoir atop which a silicic melt lens had formed and expanded. Subsequent eruptions of oxidized dacitic magmas from the Choshuenco cone from 11.5 to 8 ka were followed by andesitic to dacitic eruptions at the more southerly Mocho cone, as well as small flank vent eruptions of basaltic andesite at 2.5 and 0.5 ka. This complex history reflects a multi-reservoir plumbing system beneath Mocho-Choshuenco, which is characterized by depths of magma storage, oxidation states, and trace element compositions that vary over short periods of time (<2 k.y.). 

Many intraplate oceanic islands undergo “rejuvenated” volcanism following the main edifice-building stage. Honolulu features Hawaiʻi’s most recent rejuvenated volcanism. K-Ar dating of Honolulu volcanism suggests that it started at ca. 750 ka and ended at <100 ka. Here, we present new 40Ar/39Ar ages and olivine diffusion modeling from Koko Rift lavas to resolve when the most recent Honolulu eruptions occurred and to evaluate possible mechanisms of rejuvenated volcanism and volcanic hazards. Diffusion modeling of olivine zoning profiles in Koko Rift basalts suggests that magmas were stored in the crust for many months prior to eruption. Six new 40Ar/39Ar ages cluster at 67 ± 2 ka (2σ), which demonstrates that Koko Rift is Hawaiʻi’s youngest known area of rejuvenated volcanism. The timing of Koko Rift eruptions coincides with the pronounced drop in global sea level (∼100 m) during Marine Isotope Stage 4. This major sea-level fall may have triggered the eruptions of Koko Rift magmas that were stored in the crust for months to years at < 15 km depth. The proposed mechanism is similar to that at other volcanic islands, which suggests that changes in global sea level may have significant control on the magnitude and frequency of eruptions at ocean island volcanoes. 

The Wilkins Peak Member (WPM) of the Green River Formation in Wyoming, USA, comprises alternating lacustrine and alluvial strata that preserve a record of terrestrial climate during the early Eocene climatic optimum. We use a Bayesian framework to develop age-depth models for three sites, based on new 40Ar/39Ar sanidine and 206Pb/238U zircon ages from seven tuffs. The new models provide two- to ten-fold increases in temporal resolution compared to previous radioisotopic age models, confirming eccentricity-scale pacing of WPM facies, and permitting their direct comparison to astronomical solutions. Starting at ca. 51 Ma, the median ages for basin-wide flooding surfaces atop six successive alluvial marker beds coincide with short eccentricity maxima in the astronomical solutions. These eccentricity maxima have been associated with hyperthermal events recorded in marine strata during the early Eocene. WPM strata older than ca. 51 Ma do not exhibit a clear relationship to the eccentricity solutions, but accumulated 31%−35% more rapidly, suggesting that the influence of astronomical forcing on sedimentation was modulated by basin tectonics. Additional high-precision radioisotopic ages are needed to reduce the uncertainty of the Bayesian model, but this approach shows promise for unambiguous evaluation of the phase relationship between alluvial marker beds and theoretical eccentricity solutions. 

Rhyolitic melt that fuels explosive eruptions often originates in the upper crust via extraction from crystal-rich sources, implying an evolutionary link between volcanism and residual plutonism. However, the time scales over which these systems evolve are mainly understood through erupted deposits, limiting confirmation of this connection. Exhumed plutons that preserve a record of high-silica melt segregation provide a critical subvolcanic perspective on rhyolite generation, permitting comparison between time scales of long-term assembly and transient melt extraction events. Here, U-Pb zircon petrochronology and 40 Ar/ 39 Ar thermochronology constrain silicic melt segregation and residual cumulate formation in a ~7 to 6 Ma, shallow (3 to 7 km depth) Andean pluton. Thermo-petrological simulations linked to a zircon saturation model map spatiotemporal melt flux distributions. Our findings suggest that ~50 km 3 of rhyolitic melt was extracted in ~130 ka, transient pluton assembly that indicates the thermal viability of advanced magma differentiation in the upper crust. 

Abstract Since the publication of 40Ar/39Ar dates from Cretaceous bentonites in the Western Interior Basin by J.D. Obradovich in 1993 and in Japan by J.D. Obradovich and colleagues in 2002, improvements in the 40Ar/39Ar method have included a shift to astronomically calibrated ages for standard minerals and development of a new generation of multi-collector mass spectrometers. Thus, the 40Ar/39Ar chronometer can yield results that are synchronous with U-Pb zircon dates and astrochronologic age models for Cretaceous strata. Ages determined by Obradovich have ± 2σ analytical uncertainties of ± 400 ka (excluding J value or systematic contributions) that have been used to discriminate stratigraphic events at ca. 1 Ma resolution. From among several dozen sanidine samples, 32 of which were dated by Obradovich in 1993, we present new multi-collector 40Ar/39Ar ages that reduce the average analytical uncertainties by nearly an order of magnitude. These new ages (where the uncertainties also include the contribution of the neutron fluence J value) include: Topmost Bentonite, Mowry Shale, Kaycee, Wyoming, USA, 97.52 ± 0.09 Ma Clay Spur Bentonite, Mowry Shale, Casper, Wyoming, 98.17 ± 0.11 Ma Arrow Creek Bentonite, Colorado Shale, Montana, USA, 99.12 ± 0.14 Ma Upper Newcastle Sandstone, Black Hills, Wyoming, 99.49 ± 0.07 Ma Middle Newcastle Sandstone, Black Hills, Wyoming, 99.58 ± 0.12 Ma Shell Creek Shale, Bighorn Basin, Crow Reservation, Wyoming, 99.62 ± 0.07 Ma Shell Creek Shale, Bighorn Basin, Greybull, Wyoming, 99.67 ± 0.13 Ma Shell Creek Shale, Bighorn Basin, Lander, Montana, 100.07 ± 0.07 Ma Muddy Sandstone, Wind River Basin, Wyoming, 101.23 ± 0.09 Ma Thermopolis Shale, Bighorn Basin, Wyoming, 101.36 ± 0.11 Ma Vaughn Member, Blackleaf Formation, Sweetgrass Arch, Montana, 102.68 ± 0.07 Ma Taft Hill Member, Blackleaf Formation, Sweetgrass Arch, Montana, 103.08 ± 0.11 Ma Base of the Skull Creek Shale, Black Hills, Wyoming, 104.87 ± 0.10 Ma Thermopolis Shale, Bighorn Basin, Wyoming, 106.37 ± 0.11 Ma A new U-Pb zircon age of 104.69 ± 0.07 Ma from the Skull Creek Shale at Dinosaur Ridge, Colorado, USA, is close to the new 40Ar/39Ar age of the Skull Creek Shale in the Black Hills, Wyoming, but 5 m.y. is missing in the unconformity between the Skull Creek Shale of the Black Hills and the overlying Newcastle Sandstone. Considering the average total uncertainties that include decay constant and standard age or tracer composition for the 40Ar/39Ar (± 0.19 Ma) and the U-Pb (± 0.13 Ma) ages does not alter this finding. Moreover, the lower Thermopolis Shale in the Bighorn Basin is 1.5 Ma older than the Skull Creek Shale in the Black Hills. The 100.07 ± 0.07 Ma Shell Creek Bentonite in Montana is close to the Albian–Cenomanian boundary age of 100.2 ± 0.2 Ma of Obradovich and colleagues from Hokkaido, Japan, and 100.5 ± 0.5 Ma adopted in the 2012 geological time scale of J.G. Ogg and L.A. Hinnov. Our findings indicate that correlations based on similarity of lithology, without independent radioisotopic ages or detailed biostratigraphic constraints, can be problematic or invalid. There is much more time missing in unconformities than has been previously recognized in these important, petroleum-bearing reservoir strata. 

Abstract The Eocene Huitrera Formation of northwestern Patagonia, Argentina, is renowned for its diverse, informative, and outstandingly preserved fossil biotas. In northwest Chubut Province, at the Laguna del Hunco locality, this unit includes one of the most diverse fossil floras known from the Eocene, as well as significant fossil insects and vertebrates. It also includes rich fossil vertebrate faunas at the Laguna Fría and La Barda localities. Previous studies of these important occurrences have provided relatively little sedimentological detail, and radioisotopic age constraints are relatively sparse and in some cases obsolete. Here, we describe five fossiliferous lithofacies deposited in four terrestrial depositional environments: lacustrine basin floor, subaerial pyroclastic plain, vegetated, waterlogged pyroclastic lake margin, and extracaldera incised valley. We also report several new 40Ar/39Ar age determinations. Among these, the uppermost unit of the caldera-forming Ignimbrita Barda Colorada yielded a 40Ar/39Ar age of 52.54 ± 0.17 Ma, ∼6 m.y. younger than previous estimates, which demonstrates that deposition of overlying fossiliferous lacustrine strata (previously constrained to older than 52.22 ± 0.22 Ma) must have begun almost immediately on the subsiding ignimbrite surface. A minimum age for Laguna del Hunco fossils is established by an overlying ignimbrite with an age of 49.19 ± 0.24 Ma, confirming that deposition took place during the early Eocene climatic optimum. The Laguna Fría mammalian fauna is younger, constrained between a valley-filling ignimbrite and a capping basalt with 40Ar/39Ar ages of 49.26 ± 0.30 Ma and 43.50 ± 1.14 Ma, respectively. The latter age is ∼4 m.y. younger than previously reported. These new ages more precisely define the age range of the Laguna Fría and La Barda faunas, allowing greatly improved understanding of their positions with respect to South American mammal evolution, climate change, and geographic isolation.